Bis(η5-1-tert-butylindenyl)nickel(II)
نویسندگان
چکیده
The title compound, [Ni(C(13)H(15))(2)], shows a slightly distorted sandwich structure with two independent mol-ecules in the asymmetric unit. Both Ni atoms are located on crystallographic centres of inversion.
منابع مشابه
High-spin Cyclopentadienyl Complexes, Part 6. σ/π-Rearrangement of Aryl Ligands Connected to Cyclopentadienyliron Fragments
Dimeric tri(tert-butyl)cyclopentadienyliron(II) bromide [Cp′′′Fe(μ-Br)]2 (1) reacts with phenylmagnesium bromide to give the dinuclear di(cyclohexadienylidene) complex [(Cp′′′Fe)2(μ ,η5:η5H5C6=C6H5)] (2), and with mesitylmagnesium bromide either to the dinuclear complex [Cp′′′Fe(μ ,η5:η1-C6H2Me3)Fe(Br)Cp′′′] (3) or to the mononuclear mesityl complex [Cp′′′FeC6H2Me3] (4), depending on the reacti...
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